Novel facile routes for synthesis and isolation of fluorofullerenes C 60F18 and C60F20 based on commercially available fluorinating reagents

Pavel A. Troshin, Alexey B. Kornev, Alexander S. Peregudov, Sergey A. Baskakov, Rimma N. Lyubovskaya

Результат исследований: Вклад в журналСтатьярецензирование

8 Цитирования (Scopus)

Аннотация

We have investigated fluorination of [60]fullerene by binary and some tertiary mixtures of readily available Mn(III) and Co(III) fluorides with alkali metal fluorides and MnF2. Facile synthetic routes to fluorofullerenes C60F18 and C60F20 were developed with reaction yields up to 25 and 4%, respectively. Successful separation of fluorofullerenes, bulk isolation of C60F18 as well as some other fluorinated species have been achieved for the first time using column chromatography on silica.

Язык оригиналаАнглийский
Страницы (с-по)1559-1564
Число страниц6
ЖурналJournal of Fluorine Chemistry
Том126
Номер выпуска11-12
DOI
СостояниеОпубликовано - дек. 2005
Опубликовано для внешнего пользованияДа

Fingerprint

Подробные сведения о темах исследования «Novel facile routes for synthesis and isolation of fluorofullerenes C 60F18 and C60F20 based on commercially available fluorinating reagents». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать