The double molybdate Na9Sc(MoO4)6 refined from powder XRD data

Aleksandra A. Savina, Vladimir A. Morozov, Olga M. Basovich, Elena G. Khaikina, Bogdan I. Lazoryak

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Na9Sc(MoO4)6 {nonasodium scandium hexakis[tetraoxidomolybdate(II)]} was synthesised by a solid-state method. The basic structure units are polyhedral clusters composed of an ScO6 octahedron and three NaO6 octahedra sharing total edges. The clusters are connected by sharing vertices with bridging MoO4 tetrahedra, forming a three-dimensional framework where the cavities are occupied by the other two crystallographically independent Na atoms.

Original languageEnglish
Pages (from-to)1301-1303
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume69
Issue number11
DOIs
Publication statusPublished - Nov 2013
Externally publishedYes

Keywords

  • crystal structure
  • double molybdate
  • MoO tetrahedron
  • NaO octahedron
  • polyhedral clusters
  • powder diffraction
  • ScO6 octahedron

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