Target-aimed synthesis of anion-deficient perovskites

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The brownmillerite-type A2B2O5 structure is considered as a parent one, giving rise to different derivatives: layered double perovskites, A-site and anion-vacancy-ordered perovskites, and the perovskite-like compounds with crystallographic shear planes. The structural relationships and synthesis pathways for these classes of materials are discussed with particular attention to the ordering at the A or B sublattices, anion vacancy ordering, and their mutual interaction.

Original languageEnglish
Pages (from-to)8543-8552
Number of pages10
JournalInorganic Chemistry
Issue number19
Publication statusPublished - 6 Oct 2008
Externally publishedYes


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