Solvates of the fluorofullerenes C60F46 and C60F48 with aliphatic hydrocarbons

P. A. Troshin, Yu A. Mackeyev, N. V. Chelovskaya, Yu L. Slovokhotov, O. V. Boltalina, L. N. Sidorov

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The binary systems fluorofullerene - aliphatic hydrocarbon with normal structure were studied. The fluorofullerenes C60F46 and C60F48 were found to form molecular solvates with n-pentane, n-hexane, n-heptane, n-nonane, n-decane and n-undecane. Thermal gravimetry was used to estimate the mole composition of the solvates, differential scanning calorimetry - the dynamics of their decomposition and X-ray powder diffraction - the crystal structure of the solvates. The solubility of C60F48 in alkanes at room temperature was determined and dependence of solubility upon properties of solvates was shown.

Original languageEnglish
Pages (from-to)501-517
Number of pages17
JournalFullerene Science and Technology
Volume8
Issue number6
DOIs
Publication statusPublished - 2000
Externally publishedYes

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