Optimal cyclotron radius for high resolution FT-ICR spectrometry

Michael V. Gorshkov, Eugene N. Nikolaev

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)

Abstract

Many factors shift the cyclotron frequency of ions trapped in a Fourier transform ion cyclotron resonance (FT-ICR) trap. The major factors are radial components of the trapping electric field, ion axial displacements from the center of the trap, space charge density, and relativistic mass increase. It is shown that the ion post-excitation radius is the most crucial factor that influences the cyclotron frequency. For an elongated cyclindrical FT-ICR trap, the analytical expressions of the cyclotron frequency shifts for the various factors are derived. They are useful for precise mass measurements carried out on an FT-ICR mass spectrometer.

Original languageEnglish
Pages (from-to)1-8
Number of pages8
JournalInternational Journal of Mass Spectrometry and Ion Processes
Volume125
Issue number1
DOIs
Publication statusPublished - 24 May 1993
Externally publishedYes

Keywords

  • Cyclotron radius
  • Fourier transform mass spectrometry
  • FT-ICR

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