Novel synthetic route to fluorofullerenes: Reaction with binary and complex lead fluorides

P. A. Troshin, O. V. Boltalina, N. V. Polyakova, Z. E. Klinkina

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

We have recently developed methods of preparation of fluorofullerenes with specific fluorine content. Our previous successful synthesis of C60F36 and C60F18 with the use of transition metal fluorides inspired us to probe other high oxidation metal fluorides. In this work we report on the use of the binary lead fluorides (PbF2, PbF4, Pb2F6) and their complexes with alkali metal and alkaline earth metal fluorides (M2PbF6, M3PbF7 and M′PbF6) as fluorinating reagents for fullerenes.

Original languageEnglish
Pages (from-to)157-163
Number of pages7
JournalJournal of Fluorine Chemistry
Volume110
Issue number2
DOIs
Publication statusPublished - 2001
Externally publishedYes

Keywords

  • Fluorination
  • Fluorofullerene
  • Fullerene
  • Lead fluorides
  • Preparation

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