New perovskite-based manganite Pb2Mn2O5

Joke Hadermann, Artem M. Abakumov, Tych Perkisas, Hans D'Hondt, Haiyan Tan, Johan Verbeeck, Vladimir P. Filonenko, Evgeny V. Antipov, Gustaaf Van Tendeloo

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10 Citations (Scopus)

Abstract

A new perovskite based compound Pb2Mn2O5 has been synthesized using a high pressure high temperature technique. The structure model of Pb2Mn2O5 is proposed based on electron diffraction, high angle annular dark field scanning transmission electron microscopy and high resolution transmission electron microscopy. The compound crystallizes in an orthorhombic unit cell with parameters a=5.736(1) ≈√2ap, b=3.800(1) ≈ap, c=21.562(6) ≈4√2ap (apthe parameter of the perovskite subcell) and space group Pnma. The Pb2Mn2O5 structure consists of quasi two-dimensional perovskite blocks separated by 1/2[110]p(101)p crystallographic shear planes. The blocks are connected to each other by chains of edge-sharing MnO5 distorted tetragonal pyramids. The chains of MnO5 pyramids and the MnO 6 octahedra of the perovskite blocks delimit six-sided tunnels accommodating double chains of Pb atoms. The tunnels and pyramidal chains adopt two mirror-related configurations ("left" L and "right" R) and layers consisting of chains and tunnels of the same configuration alternate in the structure according to an -LRLR-sequence. The sequence is sometimes locally violated by the appearance of -LL- or -RR-fragments. A scheme is proposed with a JahnTeller distortion of the MnO6 octahedra with two long and two short bonds lying in the ac plane, along two perpendicular orientations within this plane, forming a d-type pattern.

Original languageEnglish
Pages (from-to)2190-2195
Number of pages6
JournalJournal of Solid State Chemistry
Volume183
Issue number9
DOIs
Publication statusPublished - Sep 2010
Externally publishedYes

Keywords

  • Crystallographic shear plane
  • Lone pair
  • Manganite
  • Perovskite
  • TEM

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