Modeling of the non-adiabatic E0g+ → D0u+ transitions induced by Ar in molecular iodine: A first attempt

Timur V. Tscherbul, Alexei A. Buchachenko

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

The non-adiabatic transitions between the first-tier E and D ion-pair states of iodine molecule induced by collisions with Ar atom are investigated using first-order semiclassical perturbation theory. PES's and diabatic couplings between electronic states are obtained in analytical form by the first-order perturbation theory-diatomics-in-molecule method. Electronic and vibrationally inelastic rate constants and product state distributions are calculated and compared with available experimental data.

Original languageEnglish
Pages (from-to)563-571
Number of pages9
JournalChemical Physics Letters
Volume370
Issue number3-4
DOIs
Publication statusPublished - 14 Mar 2003
Externally publishedYes

Fingerprint

Dive into the research topics of 'Modeling of the non-adiabatic E0g+ → D0u+ transitions induced by Ar in molecular iodine: A first attempt'. Together they form a unique fingerprint.

Cite this