Microstructural aspects of the degradation behavior of SnO2 -based anodes for aluminum electrolysis

Sergey Yu Vassiliev, Veronika K. Laurinavichute, Artem M. Abakumov, Vitaliy A. Govorov, Evgeny B. Bendovskii, Stuart Turner, Alexander Yu Filatov, Vadim P. Tarasovskii, Andrey G. Borzenko, Anastasiya M. Alekseeva, Evgeny V. Antipov

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

The performance of SnO2 ceramic anodes doped with copper and antimony oxides was examined in cryolite alumina melts under anodic polarization at different cryolite ratios, temperatures, times, and current densities. The corroded part consists of a narrow strong corrosion zone at the anode surface with damage of the intergrain contacts and a large increase in porosity, a wider moderate corrosion zone with a smaller porosity increase, and a Cu depletion zone, where the ceramic retains its initial microstructure and a slight porosity increase occurs due to the removal of the Cu-rich inclusions. Mechanical destruction of the anode was never observed in the 10-100 h tests. A microstructural model of the ceramic was suggested, consisting of grains with an Sb-doped SnO2 grain core surrounded by an ∼200 to 500 nm grain shell where SnO2 was simultaneously doped with Sb and Mn+ (M= Cu2+, Fe3+, Al3+). The grains were separated by a few nanometers thick Cu-enriched grain boundaries. Different secondary charge carrier (holes) concentrations and electric conductivities in the grain core and grain shell result in a higher current density at the intergrain regions that leads to their profound degradation, especially in the low temperature acidic melt.

Original languageEnglish
Pages (from-to)C178-C186
JournalJournal of the Electrochemical Society
Volume157
Issue number5
DOIs
Publication statusPublished - 2010
Externally publishedYes

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