Isomeric interconversion in the linear Cl--HD anion complex

R. L. Wilson, Z. M. Loh, D. A. Wild, E. J. Bieske, A. A. Buchachenko

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

The isomeric interconversion in the linear Cl--HD anion complex was discussed using the rotationally resolved infrared photodissociation spectrum. It was found that the (vHD = 0, n = 0) and (vHD = 0, n = 1) states were predominantly associated with the linear Cl- ··· DH and Cl- ···HD geometries respectively. A global fit to the transition frequencies taking the lower and upper state perturbations into account, yielded zero-order rotational and centrifugal distortion constant. The importance of quantum mechanical interconversion between two isomeric structures of a simple anion complex was also elaborated.

Original languageEnglish
Pages (from-to)2085-2093
Number of pages9
JournalJournal of Chemical Physics
Volume121
Issue number5
DOIs
Publication statusPublished - 1 Aug 2004
Externally publishedYes

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