Half- and full-collision VT energy transfer in the He-Br2(B) system

A. A. Buchachenko, T. Gonzalez-Lezana, M. I. Hernandez, G. Delgado-Barrio, P. Villarreal, N. F. Stepanov

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The ability of model interaction potentials, inverted from spectroscopic data on the He ... Br2 (B0+u) van der Waals complex, to reproduce vibrationally inelastic He + Br2(B) collision rates is examined. It is found that spectroscopic potentials which quantitatively describe vibrational predissociation of the complex (or half-collision VT energy transfer) are valid for full-collision VT rate constants as well. The sensitivity of half- and full-collision rate coefficients to the variations of potential parameters is analyzed.

Original languageEnglish
Pages (from-to)448-454
Number of pages7
JournalChemical Physics Letters
Volume269
Issue number5-6
DOIs
Publication statusPublished - 9 May 1997
Externally publishedYes

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