Generalized Stokes-Einstein-Debye relation for charged Brownian particles in solution

N. V. Brilliantov, V. P. Denisov, P. L. Krapivsky

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

The generalized Stokes-Debye-Einstein relation for the rotational diffusion coefficient of charged Brownian particles strongly interacting with dipolar solvent molecules, is evaluated. The problem is treated in terms of generalized electrohydrodynamics with microscopic expressions for molecular variables. Our results are based on the exact solution of generalized Hubbard-Onsager electrohydrodynamic equations.

Original languageEnglish
Pages (from-to)293-304
Number of pages12
JournalPhysica A: Statistical Mechanics and its Applications
Volume175
Issue number2
DOIs
Publication statusPublished - 1 Jul 1991
Externally publishedYes

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