Elementary stage rate coefficients of the full system of kinetic equations describing heterogeneous catalytic recombination of the dissociated air on the surfaces of thermal protective ceramic coatings of β-cristobalite and α-Al2O3 are determined using the quantum-mechanical calculations within the framework of cluster models and literature data. Both the impact and associative recombination processes of adsorbed oxygen and nitrogen atoms are taken into account.
- Density functional method
- Heterogeneous catalytic reactions
- Quantum mechanics
- Reusable thermal protective coatings of spacecrafts