The Green's function method in the atomic sphere approximation (ASA-KKR) is used to calculate the electronic structure of intermetallic compound VRu (CsCl lattice) both in stoichiometric composition and with small (up to 5%) deviation from stoichiometry. The results are used to interpret X-ray emission K// beta //5-spectra of V in those compounds. The influence of the nearest neighborhood of the irradiating atom in the crystal on the electronic structure and shape of the experimental emission spectra is examined.
|Number of pages||5|
|Journal||Physics of Metals and Metallography|
|Publication status||Published - 1986|