Efficient 2+3 cycloaddition approach to synthesis of pyridinyl based [60] fullerene ligands

Pavel A. Troshin, Sergey I. Troyanov, Grigoriy N. Boiko, Rimma N. Lyubovskaya, Alexandr N. Lapshin, Nataliya F. Goldshleger

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

[60]Fullerene reacts with azomethine ylids generated from 2- and 4-picolylamines to form corresponding fulleropyrrolidines bearing pyridinyl substituents. X-ray single crystal structure of the first dyad formed via coordination of ZnTPP to the fulleropyrrolidine nitrogen is reported.

Original languageEnglish
Pages (from-to)413-419
Number of pages7
JournalFullerenes Nanotubes and Carbon Nanostructures
Volume12
Issue number1-2
DOIs
Publication statusPublished - 2 Jan 2005
Externally publishedYes

Keywords

  • Azomethine ylids
  • Fullerene-metalloporphyrin dyads
  • Fulleropyrrolidines
  • ZnTPP

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