Dimethyl sulfoxide as a novel thermodynamic inhibitor of carbon dioxide hydrate formation

Anton P. Semenov, Rais I. Mendgaziev, Andrey S. Stoporev, Vladimir A. Istomin, Daria V. Sergeeva, Timur B. Tulegenov, Vladimir A. Vinokurov

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1 Citation (Scopus)

Abstract

The paper investigates dimethyl sulfoxide (DMSO) as a promising inhibitor of gas hydrates. The equilibrium conditions of the CO2 hydrate were measured over a broad range of temperatures (from 243 K to 283 K) and DMSO concentrations (up to 50 mass%). DMSO decreases the thermodynamic stability of the CO2 hydrate. Thermodynamic coherence of new hydrate equilibria data was demonstrated. The sI hydrate, crystalline ice Ih, and solid CO2 phases were identified using PXRD at 143 K. Measured unit cell parameter for sI hydrate (11.86 Å) coincided with the pure sI CO2 hydrate literature value. The DMSO inhibition activity grows much faster in water solution in comparison to lower alcohols. We explain this behavior by the more pronounced non-ideality of DMSO water solutions. Thus, DMSO can be considered an effective thermodynamic inhibitor of the formation of CO2 hydrate, superior in anti-hydrate activity to alcohol THIs within a specific range.

Original languageEnglish
Article number117670
JournalChemical Engineering Science
Volume255
DOIs
Publication statusPublished - 29 Jun 2022

Keywords

  • Carbon dioxide
  • Dimethyl sulfoxide
  • Gas hydrates
  • Phase equilibria
  • Thermodynamic hydrate inhibitor

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