The electrochemical deposition of molybdenum-rhenium oxides, Mo xRe1-xC3, from acidic peroxo-polymolybdo- perrhenate solutions is described. The presence of perrhenate in the deposition solution is observed to accelerate the electrodeposition rate of Mo xRe1-xO3 in comparison to that seen for MoO3. Cyclic voltammetry, spectroelectrochemistry, and electrochemical quartz crystal microbalance (EQCM) experiments are used to understand the electrodeposition mechanism.
|Title of host publication||ECS Transactions - Electrochemistry of Novel Electrode Materials for Energy Conversion and Storage|
|Number of pages||10|
|Publication status||Published - 2008|
|Event||Electrochemistry of Novel Electrode Materials for Energy Conversion and Storage - 211th ECS Meeting - Chicago, IL, United States|
Duration: 6 May 2007 → 11 May 2007
|Conference||Electrochemistry of Novel Electrode Materials for Energy Conversion and Storage - 211th ECS Meeting|
|Period||6/05/07 → 11/05/07|