Arbuzov chemistry with chlorofullerene C60Cl6: A powerful method for selective synthesis of highly functionalized [60]fullerene derivatives

Anastasiya A. Yurkova, Ekaterina A. Khakina, Sergey I. Troyanov, Alexander Chernyak, Lyubov Shmygleva, Alexander S. Peregudov, Vyacheslav M. Martynenko, Yury A. Dobrovolskiy, Pavel A. Troshin

Research output: Contribution to journalArticlepeer-review

43 Citations (Scopus)

Abstract

We report Arbuzov-type reactions of chlorofullerene C60Cl6with trialkyl phosphites producing highly functionalized fullerene derivatives C60[P(O)(OR)2]5H with high yields. The designed family of [60]fullerene phosphonic acids and their esters showed unusual properties which might find valuable material science applications.

Original languageEnglish
Pages (from-to)8916-8918
Number of pages3
JournalChemical Communications
Volume48
Issue number71
DOIs
Publication statusPublished - 8 Aug 2012
Externally publishedYes

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