Ab initio zero electron kinetic energy spectroscopy of the ArCl- and KrCl- anions

A. A. Buchachenko, M. M. Szczȩśniak, Grzegorz Chałasiński

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

The simulations of the zero electron kinetic energy spectra of the ArCl- and KrCl- anions were done using high-quality ab initio potentials. The difference in the electronic photodetachment transition dipole moments for distinct electronic states of the neutral, rotational structure of vibronic bands and importance of vibrational-rotational coupling were analyzed. The ab initio simulation results were found to be in agreement with the measured spectra.

Original languageEnglish
Pages (from-to)9929-9937
Number of pages9
JournalJournal of Chemical Physics
Volume114
Issue number22
DOIs
Publication statusPublished - 8 Jun 2001
Externally publishedYes

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